Requirements for the management of timesensitive chemicals were clarified in the 2011 edition. A number 04 or an abbreviation is added to each square indicating the order of hazard severity. These fullcolor nfpa 704 explanation guides will help you. Slightly hazardous in case of skin contact irritant, permeator, of eye contact irritant, of ingestion. It identifies the hazards of a material and the degree of severity of the health, flammability, and instability hazards. Chemical manufacturers and importers will be required to provide a.
Hazardous materials that are classified in more than one hazard category, as set forth in section 4. The national fire protection agency nfpa, in section 704 of the national fire code, specifies a system for identifying hazards associated with various materials. Do not use the hazard category numbers given in section 2 of. Wear chemical safety goggles, safety glasses or face shield. Nfpa chemical hazard label nfpa rating the national fire protection association nfpa has developed a standard system ansinfpa 704 for indicating the health, flammability, and reactivity hazards of chemicals. Many top quality nfpa chemical hazard labels sodium hypochlorite are in stock and ready to ship now. Nfpa divides flammability and instability hazards into two separate numbers on the label. Nfpa 1, fire code nfpa 30, flammable and combustible liquids code nfpa 45, standard on fire protection for laboratories using chemicals nfpa 55, compressed gases and cryogenic fluids codes nfpa 400, hazardous materials code in addition, some facilities choose to utilize the nfpa 704 placards regardless of actual requirements in order to provide additional information on the hazards of the materials on site. Chemical labels are available in paper to help you balance your costquality label needs.
Nfpa, hmis and oshas ghs aligned hazard communication. The national fire protection association nfpa developed a hazard identification system for emergency responders that is still in use today. Nfpa 704 302acid label decal, 10 inch vinyl for hazmat. Chemicals like potassium, magnesium, rubidium, and cesium that will explode, burn, or give off dangerous gases when exposed to water have this symbol. Memorandum on labeling of hazardous chemicals for bulk shipments pdf. Nfpa rating the national fire protection association nfpa has developed a standard system ansinfpa 704 for. Standard system for the identification of the hazards of materials for emergency response is a standard maintained by the u. Oshas hazard communication standard hcs requires the development and. Testosterone c19h28o2 cid 60 structure, chemical names, physical and. Northern label manufactures nfpa chemical labels for labeling all of your containers and drums. Hazmat guide for first responders homeland security digital library.
Collect information on hazards from applicable sections of sds. It is printed with bold colors on a white background to make your nfpa hazard rating clear to emergency responders. Nfpa uses a symbol system designed as a diamondshaped label containing four differently colored squares. Nfpa chemical labels, nfpa diamond labels, chemical hazard. Department of transportation hazard labels, and a general description of the chemical. Proper identification of such hazards is essential for anyone who needs to handle such materials, and emergency responders. For those that have the potential to be quite dangerous, however, the national fire protection association nfpa has. Nfpa chemical hazard label health reactivity stability flammability 9. The national fire protection association nfpa in the united states uses a standard called nfpa 704 as a chemical hazard label. Msds for acetone handout electronic version is a separate pdf file how to. Chemical nfpa 704 explanation guide signs and labels. Frequently asked questions on nfpa 704 standard system for the.
Nfpa 704 diamond with 1400 hazard level indicators. To look up a rating for a particular chemical click on the link at the bottom of the page. Standard on fire protection for laboratories using chemicals. In addition, a special precaution symbol may be used where necessary.
Care facilities, 2005 edition were added to nfpa 45. Alternative labeling systems such as the national fire protection association nfpa 704 hazard rating and the hazardous material information system hmis are permitted for workplace containers. Nfpa 704 sometimes is called a fire diamond because the diamondshaped sign indicates flammability of a substance and also communicates essential information about how. In the past some chemical manufacturers used nfpa diamonds on their products, but now labels are required to use ghs labeling. Only select registry of toxic effects of chemical substances rtecs data is presented here. National fire protection association hazard identification system. Guidance on the allocation of the hazard communication label. Learn the national fire protection association s chemical hazard labels chemicals are a part of our everyday life, but not all of them are necessarily dangerous or flammable. Choose labelmasters nfpa standard labels when you need to ensure compliance with nfpa 704. The nfpa committee recognized the widespread lack of. Specific chemical labels and fillintheblank labels are available. National fire protection association, technical committee on classification and properties of hazardous chemicals data, doi 10. Standard on the fundamentals of combustible dust 2016 edition.
The system uses a colorcoded diamond with four quadrants in which numbers are used in the upper three quadrants to signal the degree of health hazard blue, flammability hazard red, and reactivity hazard yellow. Select from our comprehensive line of highquality, preprinted chemical hazard labels. Write in the nfpa hazard codes in the diamond spaces and check off substance characteristics, severity of health hazards, and personal protective equipment. Hazardous materials incidents are different from fire suppression or other usual. They list the chemical name, the cas chemical abstracts service number and ratings for health, flammability, instability and specific hazard symbols. In this volume, defined as the equivalent of nfpa flammability.
When describing components of the hcsghs, note that the greater the chemical hazard severity, the lower the hazard number. Supplemental information may also appear on the label such as any hazards not otherwise. The revised regulation precludes sole use of the nfpa 704 label as a standalone hazcom labeling system. Chapter 8 of nfpa 704 osha hazard communication standard 29 cfr 1910. When data submitted in accordance with the requirements set forth in. Numbers are used to classify hazards to determine what label information is required. Safety data sheet according to 29cfr19101200 and ghs rev. Nfpa chemical identification label identify hazardous chemicals by labeling their features on an easy to use format. The nfpa 704 standard of the national fire code provides a simple system for identifying hazards associated with various materials in case of a fire, spill or other emergency.
Warningprovides specific criteria for classification of health, physical and environmental hazards, as well as classification of mixtures. Designed for easy identification of chemical hazards by firefighters and emergency responders concerned with burning, spilled or exploding materials, these pressuresensitive paper and pvcfree vinyl labels are printed with lightfast ink and proven adhesives. Nfpas guy colonna explains a few key differences between the hazard labeling guidelines in nfpa 704, identification of the hazard of materials for. This indicates a potential hazard using water to fight a fire involving this material. W the w symbol indicates that the chemical being labeled has a strong reaction to water. Teacher notes activity understanding msds and nfpa summary students will learn the basic information displayed on msds and chemical hazard labels.
Nfpa 704 placard chemical hazard ratings 2373 circadian way, santa rosa, ca 95407 phone. How does the 704 label differ from other hazardous material labels. Nfpa standard labels identify chemical hazards for first. Nfpa rating and oshas classification system 04 0least hazardous 4most hazardous 14 1most severe hazard 4least severe hazard the hazard category numbers are not required to be on labels but are required on sdss in section 2.
Understanding chemical hazard labels and msds quizlet. Combustible dusts are a recognized hazard for industrial facilities everywhere, and performing a hazard analysis is the best way to evaluate your risk of an explosion. Nfpa chemical hazard labels sodium hypochlorite from seton a wide variety of nfpa chemical hazard labels sodium hypochlorite with great prices, fast shipping, and setons 100% satisfaction guarantee. The information in cameo chemicals comes from a variety of data sources. The nfpa system is characterized by the diamond shape that is actually a squareonpoint shape. Posting this hazard rating sign helps ensure that individuals in the area know how to read the nfpas rating system, making it more effective. Each of the following chemical pages is in portable document format pdf and. I need the health, fire, reactivity, and special hazards for tnt trinitrotoluene. Nfpa 704, identification of the hazards of materials for emergency response which uses a combination of color coding and numbers to describe a hazards severity provides a simple, readily recognized, and easily understood label designed to assist those who are responding to an emergency such as a fire or spill. Nfpa placard numbering is based on the relative hazards of a chemical, not on absolute values, so ratings can vary slightly between different manufacturers of the same chemical. Hazard communication occupational safety and health.
The labels do not include the manufacturers name and address. See actual entry in rtecs for complete information. Standard on fire protection for laboratories using. Nfpa chemical hazard labels sodium hypochlorite seton. National fire protection association the national fire association nfpa has developed a colorcoded number system called nfpa 704. In october 2015, the national fire protection association published the newnfpa 652. When a compound is both waterreactive and an oxidizer, the wbar symbol should go in this quadrant and the ox warning is placed immediately below the nfpa diamond. Chemical manufacturers and importers are required to provide a label that includes a harmonized signal word, pictogram and hazard statement for each hazard class and category. Your company purchases secondary containers for chemicals, which are bottles with preprinted embossed labels that contain a specific chemical name e. Page 3 of 18 special chemical health fire reactity hazard beryllium dust or powder 4 1 0 biphenyl 2 1.
These righttoknow hazardous chemical rating posters have an eyecatching design and lists ratings of 325 of the most commonly used chemicals for both the nfpa and hcmis systems. You probably have seen nfpa 704 or the fire diamond on chemical containers. Some sdss may provide the nfpa diamond symbol with hazard rating numbers filled in already. Slightly hazardous in case of skin contact irritant, permeator, of eye contact irritant, of ingestion, of inhalation.
Understanding the nfpa 704 diamond labeling system. This nfpa 302acid chemical hazard labelsticker is easy to apply just peel and stick. Also, is it acidic, alkali, an oxidizer, or corrosive or none of these. The chemical identifier fields include common identification numbers, the nfpa diamond u. Use setons nfpa diamond classification chart to label chemicals as a fire hazard, unstable, specific hazard, or health hazard to keep employees safe. All feature a strong, permanent adhesive that ensures they wont peel off. The boston fire department regulations require the national fire protection association nfpa 704 diamond to be posted on all laboratory doors. Testosterone investigated as a drug, hormone, mutagen, reproductive effector, and tumorigen. There are three symbols approved by the nfpa 704 system. First tentatively adopted as a guide in 1960, and revised several times since then, it defines the colloquial safety square or fire diamond used by. Labeling of secondary containers occupational safety and. National fire protection association hazard identification.
Nfpa and hmcis righttoknow hazardous chemicals rating chart. Classification and labelling of chemicals ghs, revision 3. First aid measures, handling and storage, fire fighting and accidental release measures, exposure control and personal protection. National fire protection association nfpa warnings. Dot symbols may also be used as labels on containers of. Paper labels are economical but contain a permanent adhesive and are great for indoor use. This surfacemount nfpa diamond with 1400 rating will help alert emergency responders to potential danger. Hazardous materials in storage or use in a laboratory work area that could present an explosion hazard were quantified. Our labels have easytoremove backing and are uv, chemical, abrasion and moisture resistant. Numbering information for each chemical is available on the chemical s safety data sheet sds. There are several widely used systems for labeling hazardous materials.